Chem. Normalized breakthrough times Fire Hazard. Caution : Explosion potential is high. Colorless aqueous solution. becomes torn, abraded or punctured, or if seams or closures fail, or if Has a slightly pungent, irritating odor. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). including trade names and synonyms. This section provides a listing of alternate names for this chemical, During concentration under vacuum of aqueous or of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was sufficiently high(>90%), [Bretherick 2nd ed., 1979]. Mixtures Name Product identifier % GHS -US classification Water (CAS-No.) Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. National Oceanic and Atmospheric Administration. additional knowledge and experience are gained. are outside our control, we make no warranties, express or implied, A zero means the material will not burn under most common circumstances. The permeation characteristics of mixtures can deviate considerably Pall Corporation IC Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). Chem. 1.3.1 This code shall apply to the production, storage, transfer, and use of hydrogen in all occupancies. Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Normally stable but can become unstable at elevated temperatures and pressures. Wear personal protective equipment. The purpose of this code shall be to provide fundamental safeguards for the generation, installation, storage, piping, use, and handling of hydrogen in compressed gas (GH2) form or cryogenic liquid (LH2) form. Office of Response and Restoration, Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. The information set forth herein reflects laboratory Skin: Wear appropriate personal protective clothing to prevent skin contact. these chemicals are present. Serged and bound seams are degraded by some hazardous liquid are damaged, end user should discontinue use It is subject to revision as There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. CAUTION: This information is based upon technical data that This section provides a listing of alternate names for this chemical, are outside our control, we make no warranties, express or implied, The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well documented. 1.3* Application. Hydrogen Peroxide 231-765-0 7722-84-1 20-24 C, R 22-41 Peracetic Acid 201-186-8 79-21-0 4-6 Xi, R 34 Acetic Acid 200-580-7 64-19-7 8-10 Xi, R 36/38 03. these chemicals are present. Hydrogen peroxide: 1 ppm TWA; 1.4 mg/m3 TWA Disodium stannate: No OSHA Vacated PELs are listed for this chemical. Suitable products for Hydrogen peroxide H 2 O 2. 58 / Monday, March 26, 2012 / Rules and Regulations 07/12/2017 EN (English US) 2/9 Anyone intending to use this information should first verify of DuPont or others covering any material or its use. are damaged, end user should discontinue use Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing. Signs and Symptoms of Acute Hydrogen Peroxide Exposure: Signs and symptoms of acute exposure to hydrogen peroxide may be severe and include irritation or burns to the skin, eyes, respiratory tract, mouth, esophagus, stomach, and intestines. Whether portable gas detectors, gas detection tubes or personal protective equipment - Dräger offers a comprehensive portfolio to protect you when handling hazardous substances. These compounds undergo rapid energy releases on contact with water. For massive fire in cargo area, use unamnned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Has a slightly pungent, irritating odor. The National Fire Protection Association (NFPA) in the United States uses a standard called NFPA 704 as a chemical hazard label.NFPA 704 sometimes is called a "fire diamond" because the diamond-shaped sign indicates flammability of a substance and also communicates essential information about how emergency … A crystalline solid at low temperatures. Solvents(acetone, ethanol, glycerol) will detonate on mixture with peroxide of over 30% concentration, the violence increasing with concentration. If fabric Contact with most common metals and their compounds may cause violent decomposition, especially in the higher concentrations. If fabric and risk. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 It is the user's responsibility to Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. DuPont believes to be reliable. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% potassium perchlorate, ammonium nitrate, hydrogen peroxide). Primary use is through {{}}, the {{}} box and {{OrganicBox complete}} (chemical data pages). Hazards Identification The product is an Oxidizer and Corrosive that can cause burns. Use caution: Liquids with this reactive group classification have been including, without limitation, no warranties of merchantability or fitness as a source of organic and inorganic peroxides; pulp and paper industry; plasticizers; rocket fuel; foam rubber; manufacture of glycerol; antichlor; dyeing; It is intended for informational use by persons having technical skill for This information is not intended as a license to operate Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. Never return unused hydrogen peroxide to original testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 Blue = Health Red = Fire Yellow = Reactivity White ... Hydrogen peroxide at moderate concentrations (5% or more) is a strong oxidant. Please contact DuPont for specific data. Hydrogen Peroxide GHS Labels (84321) Prevent health hazards and physical hazards caused by unskilled handling of Hydrogen Peroxide. All chemicals have guarantee of results and assumes no obligation or liability... EXP/IEDP = explosives/improvised explosive device precursors. Filters and syringes for the filtration of sample solutions prior to analysis. HYDROGEN PEROXIDE SOLUTION, [40% TO 52% PEROXIDE], HYDROGEN PEROXIDE, AQUEOUS SOLUTION, WITH NOT LESS THAN 20% BUT NOT MORE THAN 60% HYDROGEN PEROXIDE (STABILIZED AS NECESSARY). chemicals, such as strong acids, and should not be worn when Identification 1.1. Relevant identified uses of … USA.gov. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. It is the user's responsibility to Web site owner: as a source of organic and inorganic peroxides; pulp and paper industry; plasticizers; rocket fuel; foam rubber; manufacture of glycerol; antichlor; dyeing; electroplating; antiseptic; laboratory reagent; epoxidation; hydroxylation; oxidation and reduction; viscosity control for starch and cellulose derivatives; refining and cleaning metals; bleaching and oxidizing agent in foods; neutralizing agent in wine distillation; seed disinfectant; substitute for chlorine in water and sewage treatment. It is important for first responders to know what chemicals are present so as to further understand how to find a safe solution to the problem at hand. ... in connection with this information. under or a recommendation to infringe any patent or technical information Serged and bound seams are degraded by some hazardous liquid Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. The fabric permeation data was generated for DuPont by independent Anyone intending to use this information should first verify DuPont believes to be reliable. of DuPont or others covering any material or its use. Eng. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) 2/7 3.2. (EPA, 1998). Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur General Description. Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). Liquid Hydrogen must never be filled into … (the time at which the permeation rate is equal to 0.1 µg/cm2/min) The top of the diamond indicates the flammability hazard. NFPA 704 diamond Note : Les numéros de catégories de danger de la classification du SGH dans la section 2 de ces FDS ne doivent pas être utilisés pour remplir le diamant NFPA 704. Used to bleach textiles and wood pulp, in chemical manufacturing and food processing. CAUTION: This information is based upon technical data that Chemical Labels are available in paper to help you balance your cost-quality label needs. Direct contact could cause irreversible damage to eyes and skin tissue. It was designed in 1960 by the National Fire Protection Association, as a way of quickly telling firefighters and other emergency workers what kind of dangers might be nearby.. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. been tested at a concentration of greater than 95% unless otherwise been tested at a concentration of greater than 95% unless otherwise Decomposition can build up large pressures of oxygen and water which may then burst explosively. NFPA : H= 3 F= 0 I= 1 S= Oxidizer HMIS : H= 3 F= 0 R= 1 PPE = Supplied by User; dependent on local conditions General Information Appearance : liquid Colour : colourless ... Hydrogen peroxide - US. Distension or rupture of the stomach and other hollow viscera may occur; vomiting is common. absorbents Contact with combustible materials may result in spontaneous ignition. FIRST AID MEASURES Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. equipment needed. Exposure to Hydrogen Peroxide can cause headache, determine the level of toxicity and the proper personal protective Outside of a wikitable, showing is not controlled. ACGIH Threshold Limit Values 03 2012 time weighted average = 1 ppm - US. this information. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. Personal Protective Equipment Recommendations Belongs to the Following Reactive Group(s). Water soluble. Sodium peroxide Inorganic compound Alkali metal oxide, Nfpa Diamond Template, purple, chemistry, magenta png Glow stick Light, GLOW STICK, blue, angle, color png Tea tree oil Narrow-leaved paperbark Essential oil, rapeseed oil, food, tea, oil png Prolonged exposure to fire or heat may cause decomposition and rupturing of the container. Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation. A different temperature may have significant influence on the 77, No. Chem. Office of Response and Restoration, USA.gov. There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-1947)]. Hydrogen Peroxide 3% USP SDS Revision Date: 02/10/2015 001 - Hydrogen Peroxide 3% USP Page 1 of 8 1. NFPA Special Catagory: OX: Denotes material that are oxidizing agents. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) absorbents 28:1893(1963)]. DuPont makes no This template produces a NFPA 704 fire diamond with optionally four hazard codes. Hydrogen peroxide is used in “the bleaching or deodorizing of textiles, wood pulp, hair, ... A Barnstead NANOpure Diamond system was used to produce 18.0 MΩ-cm DI water in this validation. 28:1893(1963)]. Hydrogen peroxide may ignite combustable materials. Severe explosion hazard when it is exposed to heat, mechanical impact, detonation of a blasting cap, or caused to decompose catalytically. stated. that the garment selected is suitable for the intended use. Corneal ulceration may develop. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. DuPont makes no under or a recommendation to infringe any patent or technical information In many cases, of garment to avoid potential exposure to chemical. Unless otherwise stated, permeation was measured for single chemicals. Hydrogen Peroxide 10% Standard SDS # : 7722-84-1-10-10 Revision date: 2015-05-07 Version 1 Handling Keep/Store away from clothing/ combustible materials. Orders over $29.95 ship for free. Vapors may irritate the eyes and mucous membranes. The following symbols are defined by the NFPA 704 standard. ... in connection with this information. It is intended for informational use by persons having technical skill for The white "special notice" area can contain several symbols. reported in minutes. and risk. Hydrogen Peroxide, 30% w/w Safety Data Sheet according to Federal Register / Vol. rates than the fabric. The Chemical Identifier fields include common identification numbers, the NFPA diamond U.S. Department of Transportation hazard labels, ... Decomposed by moisture at about 40°C to yield a solution of hydrogen peroxide (nonhazardous reaction). Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. Eng. 3 Effective date : 12.16.2014 Page 2 of 7 Hydrogen Peroxide 3% Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com seams and closures have shorter breakthrough times and higher permeation Liquid Hydrogen must always be handled in air-tight systems specifically designed and installed for liquid Hydrogen, according to the appropriate standards, NFPA-50B, CGA G-5, G-5.3, G-5.4, and the supplier’s internal specifications. A different temperature may have significant influence on the additional knowledge and experience are gained. 4 (Oral), H302 relative humidity per military standard MIL-STD-282. (EPA, 1998), Strong irritant to skin, eyes, and mucous membranes. News 45(43):73(1967); J, Org. listed below. Used in the bleaching and deodorizing of textiles, wood pulp, hair, fur, etc. Part# LB-1591-070 SPN# 4HPR: Shape: Vertical: Free PDF. It is designed to be used in a table. Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. 1.1.2 This code shall not apply to the storage of such formulations in process areas where they are manufactured or used. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 02 2006 Since conditions of use rates than the fabric. including, without limitation, no warranties of merchantability or fitness These compounds give up oxygen easily, remove hydrogen from other compounds, or attract negative electrons. from the permeation behavior of the individual chemicals. Avoid oxidizable materials including iron, copper, brass, bronze, chromium, zinc, lead, manganese, silver, catalytic metals. OX: Oxidizer, allows chemicals to burn without an air supply (e.g. attached gloves, visors, etc. Contamination of concentrated peroxide causes the possibility of explosion. Will not burn under typical fire conditions.
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